Interfacial diffusion in TiN<sub>0.3</sub>/AlN composite

ZOU Qin; SUN Junrong; LI Yanguo; LUO Yong`an

doi:10.13394/j.cnki.jgszz.2022.0222

Volume 43 Issue 5

Oct. 2023

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ZOU Qin, SUN Junrong, LI Yanguo, LUO Yong`an. Interfacial diffusion in TiN0.3/AlN composite[J]. Diamond & Abrasives Engineering, 2023, 43(5): 537-545. doi: 10.13394/j.cnki.jgszz.2022.0222

Citation:

ZOU Qin, SUN Junrong, LI Yanguo, LUO Yong`an. Interfacial diffusion in TiN_0.3/AlN composite[J]. Diamond & Abrasives Engineering, 2023, 43(5): 537-545. doi: 10.13394/j.cnki.jgszz.2022.0222

ZOU Qin, SUN Junrong, LI Yanguo, LUO Yong`an. Interfacial diffusion in TiN0.3/AlN composite[J]. Diamond & Abrasives Engineering, 2023, 43(5): 537-545. doi: 10.13394/j.cnki.jgszz.2022.0222

Citation:

ZOU Qin, SUN Junrong, LI Yanguo, LUO Yong`an. Interfacial diffusion in TiN_0.3/AlN composite[J]. Diamond & Abrasives Engineering, 2023, 43(5): 537-545. doi: 10.13394/j.cnki.jgszz.2022.0222

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Interfacial diffusion in TiN_0.3/AlN composite

doi: 10.13394/j.cnki.jgszz.2022.0222

ZOU Qin^{1, 2},
SUN Junrong²,
LI Yanguo^{2
,
,},
LUO Yong`an²

1.
School of Mechanical Engineering, Yanshan University, Qinhuangdao 066004, Hebei, China
2.
Metastable Materials Science and Technology State Key Laboratory, Yanshan University, Qinhuangdao 066004, Hebei, China

Funds: Projects(ZD2021099) supported by the Science and Technology Project of Hebei Education Department

More Information

Received Date: 2022-12-19
Accepted Date: 2023-02-09
Rev Recd Date: 2023-02-04

Available Online: 2023-12-07

Abstract

Abstract

In recent years, extensive research has been conducted on nano-multilayer films of TiN/AlN system. However, there are few reports on its bulk composites. In this study, non-stoichiometric TiN_0.3 was prepared by mechanical alloying, then TiN_0.3/AlN composites were fabricated through spark plasma sintering (SPS) utilizing both layered and mixed sintering techniques. The phase composition, element distribution and microstructure of TiN_0.3/AlN composites were characterized by metallography, XRD, SEM, EDS and TEM, to study the diffusion of N atoms in the interface region of TiN_0.3/AlN composites. The results show that N in AlN diffuses into TiN_0.3 through a vacancy diffusion mechanism, The area of TiN_0.3 in contact with AlN absorbs N from AlN to make the composition close to the normal proportion of TiN, while the area "far away" from the interface is close to the component of TiN_0.3, and its diffusion degree weakens gradually. In the two-phase bonding region, there is a thin amorphous layer whose width is less than 1 nm. The electron diffraction pattern elongates longitudinally and produces coherent lattice. The AlN lattice of hexagonal structure is distorted to TiN lattice, forming TiN_0.3/AlN with a face-centered cubic structure.
- TiN/AlN composite,
- SPS,
- interface diffusion,
- cohere

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References(37)

References

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Interfacial diffusion in TiN_0.3/AlN composite

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